Electrodeionization Device And Method Comprising Control Of The Electric Current By Measurement Of Ion-Exchange Material Expansion

ABSTRACT

Device for the removal of ions from a polar liquid, e.g. water, comprising at least one compartment which comprises at least one inlet for an entering polar liquid flow and at least one outlet for an outgoing deionized liquid flow, in which said compartment an electrochemically regenerable ion-exchange material fills a zone through which zone a liquid flow is able to pass, the device being characterized in that it comprises one sensor of at least one dimensional change of the ion-exchange material. The sensor can comprise a photo-sensor or a sensor of mechanical stress. Preferably an apparatus connected to the sensor is able to analyze this dimensional change and to control the electric current. Method of using said device, whereby the electrical current applied to the device is controlled according to the expansion of the resin.

This application is a divisional of U.S. patent application Ser. No.13/155,505 filed Jun. 8, 2011, which claims priority of European PatentApplication No. 10290370.5 filed Jul. 1, 2010, the disclosures of whichare incorporated herein by reference.

The present invention pertains to a specialized electrodeionization(EDI) device and method. Such devices and methods are employed for theproduction of an at least partially deionized liquid from a polar liquidfeed stream.

Herein, “deionized” means “deanionized”, “decationized”, or “completelydeionized” (that is to say de-anionized and de-cationized) whateverdegree of deionization is achieved.

Continuous or non-continuous EDI is known in the art as a process whichremoves, at least partially, ionized and ionizable species from polarliquids, such as water, using electrically active media and an electricpotential difference to drive ion transport. Deionization takes place inat least one diluate compartment of EDI, which is a compartment in theelectrochemical device where purification, i.e. removal of contaminants,occurs.

EDI relates currently to standard water deionization techniques. Itsoriginal principle, i.e. the use of a mixed bed ion-exchange resin inthe diluate compartment of an electrodialysis stack, has beencommercialized by Millipore Corporation since 1987.

Generally, an EDI module comprises at least one couple of electrodes andcompartments, which may be separated by membranes, the diluatecompartment(s) being filled with an ion-exchange material. Typically,the compartments are alternating diluate and concentrate compartmentsand the membranes separating these compartments are ion-exchangemembranes, generally alternating anion- and cation-exchange membranes.Compartments comprising the electrodes, i.e. electrode compartments, canact as diluate or as concentrate compartments, depending on the concept.

The ion-exchange materials are generally cation- and anion-exchangematerials in the form of beads (conventional ion-exchange resins),powders, fibers (woven or non-woven textiles) and porous blocks. Theyfill a certain volume as a bed in a compartment, and allow a stream offluid to flow through the void volume as well as the electric current ofions be conducted through the ion-exchange material. They are generallyreferred to as “resins”.

Different arrangements of ion-exchange materials in diluate compartmentof an EDI are possible in the prior art. The original arrangement is amixed bed of ion-exchange resins. An alternative arrangement is thealternance of layers of cation-and anion- exchange resins, calledlayered beds. The use of cation-exchange resin and anion-exchange resinin completely separated diluate compartments, electrochemicallyregenerated in a continuous mode, is also known. In certain schemes, thefeed aqueous solution flows through the cation-exchange resin andanion-exchange resin beds in series and the H⁺ and OH⁻ ions produced forexample in the electrode reactions are used for regeneration of resins.

In known methods of EDI and related devices with electrochemicalregeneration of ion-exchange material, the liquid flow is fed in andstreams out of every compartment separately or is distributed betweenthe parallel compartments of a module through the common collectorplaced outside the compartments. Typical liquid used as feed ispre-treated water, such as reverse osmosis permeate.

When an electrical voltage is applied between electrodes, the electriccurrent of ions is conducted mainly through this ion-exchange material.The removal of ions from the feed stream is carried out directly intothe ion-exchange material, where they are exchanged with H⁺- or OH⁻-ions. During regeneration, generated H⁺ and OH⁻ ions, e.g. generated byelectrochemically enhanced water dissociation, regenerate correspondingion-exchange material while producing a concentrate as waste. A specificregeneration degree of resins is usually required to provide sufficientremoval of ionic contaminants from the ion-exchange material and, incase of application in water deionization, to produce water of highresistivity. If the regeneration degree of resins is not high enough,the resistivity of the diluate, that is to say the quality of producedwater, will decrease.

At a fixed feed water flow rate and composition, i.e. concentration ofall contaminants, the regeneration degree of ion-exchange material isproportional to the direct electric current. It should be mentioned thatthe resin in regenerated form, i.e. in H⁺-ion form for cation-exchangeresin and in OH⁻-ion form for anion-exchange resin, swells stronger,i.e. has more volume than in its (original) salt form.

If the diluate compartment of an EDI module is completely filled byresin, the increase of regeneration degree of said resin results in anexpansion of the resin and a mechanical stress on the walls of thecompartment. This stress results in compressive strain on the elementsforming the compartment, i.e. it deforms membranes, frames, flowdistributors, etc. This can lead to internal or external leaks. Moreoverthe maintaining of an electric current at a level significantly higherthan one sufficient to keep the required regeneration degree wouldresult in excessive energy consumption.

On the other hand, if the regeneration degree and volume of beddecrease, then the compartment can not be filled completely with theresin bed, and that can result in an increase of electrical resistancein the void area, fluidization of resin bed and weak mechanical supportof the membranes. All these phenomena are not advantageous for themodule performance and its life time. Moreover, an electric currentstrength, which is not high enough to create a sufficient regenerationof resins and removal of contaminants, would result in a poor waterquality produced.

Thus, for sustainable and reliable operation of an EDI module, a correctadjustment of current is required in order to prevent the abovementioned drawbacks.

Usually when the parameters of the feed water are measured, such asconductivity and concentrations of dissolved CO₂ and silicium forreverse osmosis permeate, an optimal electric current for the EDI can becalculated, taking into account a fixed flow rate. However, thecharacteristics of feed water can change over time which may be causedby the instability of upstream treatment or by quality changes of waterused by the system. Furthermore, the flow rate through the EDI apparatuscan vary during the life-time of the device. Due to all these possiblechanges, the set electric current can deviate from the optimal one andthis can cause malfunction.

Some prior art documents have pointed out the importance of electriccurrent control in an EDI device. Different parameters are usuallymonitored as a signal for the control of the electric current.

For example, patent application US 2004/060823 discloses a method forautomatically controlling the set electric current through an EDI unit.The ionic load of the water being fed to the unit is continuouslymonitored by measuring the feed water conductivity and using the outputof the conductivity meter to automatically adjust the electric currentthrough the EDI unit. The limitation of the method is that theconductivity measurement estimates only the content of ionized speciesand not of ionizable molecules. The concentration of CO₂, which is anionizable molecule, is usually comparable with concentration of saltions in a typical composition of EDI feed water. Thus, the regulation ofcurrent according to this method is not satisfactory.

U.S. Pat. No. 7,264,737 B2 discloses a water treatment system includinga boron analyzer. A controller responds to a boron concentrationdetected in the water produced, by adjusting the current or voltage inthe EDI unit and maintaining a portion of ion-exchange resin in thediluate compartment in a substantially regenerated state. However onlineboron-analyzers are expensive and they require special maintenance, thustheir use according to this patent is not an easy solution for the oneskilled in the art.

In US 2008/0156710 A1, a water producing apparatus with an EDI device,comprises sensing means, which measure water temperature at differentstages of the process, and controlling means, which control an appliedvoltage or an electric current supplied to the EDI device on the basisof these water temperatures. Since the temperature is not directlyrelated to the contaminants level, the use of temperature as a parameterfor current regulation in EDI is not satisfactory.

Thus, the prior art methods to control the electric current in an EDIapparatuses are either insufficient, or unreasonably expensive, and aneed for simple and reliable method to regulate the electric current andmaintain sufficient regeneration degree of ion-exchange material in EDIis present. Furthermore, none of these prior art documents considers oreven suggests the ion-exchange resin expansion as a parameter forcontrolling the electric current.

The solution disclosed here provides a simple way to control theelectric current in EDI device. This solution to the problem is lessexpensive and additionally provides a possibility to optimize energyconsumption (operation cost) of deionization, while providing therequired quality of produced water and avoiding mechanical damage in thedevice (such as strong membrane deformation, or internal or externalleaks).

Accordingly and advantageously, the present invention provides devicesand methods that address one or more of the issues discussed above, in asimple, efficient and cost-effective way.

The invention provides a device for the removal of ions from a polarliquid, in which the device comprises electrodes, at least onecompartment which comprises at least one inlet for an entering polarliquid flow and at least one outlet for an outgoing deionized liquidflow, in which said compartment an electrochemically regenerableion-exchange material fills a zone through which zone a liquid flow isable to pass, the device being characterized in that it comprises atleast one sensor of at least one dimensional change of the ion-exchangematerial filling said zone.

The compartment is generally a diluate compartment or purificationcompartment because it produces a purified and diluate liquid. This zoneis a purification zone or diluate zone.

A compartment is, according to the invention, composed of anion-exchange media and a frame which is a plastic element which keepsthe media inside it. The diluate compartment is a compartment in which,according to the invention, there is at least a diluate zone in whichthe deionization can take place. A module is, according to theinvention, an assembly of compartments and electrodes.

If more than one diluate compartment is comprised in the device, thenpreferably only one diluate compartment comprises, according to theinvention, the sensor of at least one dimensional change. The otherdiluate compartment(s) can comprise means for cushioning at least onedimensional change of the ion exchange material filling a sector of saidcompartment. These means are for example a spring combined with a porousflow distributor, or a flexible wall situated inside said compartment,such as a damper of said dimensional change. This would advantageouslydecrease the risk of damaging elements of said diulate compartment, suchas housing, membrane(s) and flow distributor(s). These means forcushioning would also advantageously provide an homogeneous packaging ofthe ion exchange material inside a sector of said compartment, with asuitable density and a good contact with said elements of thecompartments themselves. They would also advantageously prevent a flowchanneling while providing good electrical conductivity during a processof use of the device according to the invention.

The sensor is an element able to detect, and preferably to detect andregister, at least one dimensional change of the ion-exchange material.The sensor is generally an apparatus or a piece of an apparatus. Saiddimensional change usually occurs at a displacement of the ion-exchangematerial's boundary during the use of the device in a process for theremoval of ions from a polar liquid. Said displacement can be a lineardisplacement.

The dimensional changes of the ion-exchange material are mainly thechange of volume of said material inside the compartment, causing amechanical stress. This change of volume depends on the ionic content ofthe material. The volume of the ion-exchange material in its regeneratedform is usually larger than its volume in salt form. For example atypical cation-exchange material comprising 8% by weight ofcross-linking agent has a 7% larger volume in H⁺-ion form than that inNa⁺-ion form. A typical anion-exchange material comprising 8% ofcross-linking agent has a 20% larger volume in OH⁻ion form than that inCl⁻-ion form.

When the ion-exchange material is constituted by rigid spherical beads,these beads change their diameter with respect to their ionic form, thusleading to a corresponding change of the total volume (three dimensions)of the bed formed by these beads. For example, if a bed of ion-exchangematerial fills completely a compartment restricted on all sides bywalls, an increment of the total volume of the bed will create amechanical stress on the walls of the compartment.

The degree of expansion and the mechanical stress caused by the expandedresin is dependent on the type, the cross-linking degree and theregeneration degree of the ion-exchange material, as well as ongeometric parameters of the compartment and on the amount ofion-exchange material originally placed into this compartment. It alsovaries with temperature, mechanical properties of membranes and frames,and other parameters as known from the one skilled in the art.

A preferable location of the sensor is completely within the compartmentwhere a strongest change of resin expansion is expected.

According to the invention, the mechanical stress created by theexpansion of resin is measured by at least one sensor of mechanicalstress, for example a piezoresistive sensor, a magnetoresistive sensor,or a magnetostrictive sensor, preferably mounted into the frame of thecompartment, and is used as a parameter for the control of the electriccurrent via the resin expansion, which is a measure of the regenerationdegree. The signal of this sensor of mechanical stress is preferablyprovided to an electronic device controlling the electric currentapplied to the EDI device. The measurement of the mechanical stressinside the compartment is advantageously used to sufficiently controlthe electric current which is to be applied to the compartment toproduce water of required quality without damaging the compartment.

In a variant, the sensor comprises a sensor of mechanical stress whichis generally placed entirely inside or in contact with the zone. Forexample the sensor of mechanical stress is mounted into the frame of thecompartment, e.g. on a wall of said frame. The stress measured by saidsensor is a sum of the hydraulic water pressure inside the compartmentand an additional stress created mechanically by the ion-exchange resinmaterial which swells.

The sensor of mechanical stress can also comprise a piezoresistivesensor, a magnetoresistive sensor, a magnetostrictive sensor, or ofanother type as known from the one skilled in the art such as a linearvariable differential transformer. The sensor of mechanical stressgenerally determines the position of the ion-exchange material'sboundary, and is able to generate a signal in relation with thisposition. The signal outgoing from the sensor is typically used as aparameter for the control of the electric current.

The sensor of mechanical stress can be used in relation with supportingmembers, such as springs and plates, providing better accuracy of themechanical stress measurement. In a preferred embodiment, the positionof the ion-exchange material's boundary is fixed by a plate, supportedgenerally by a spring. In another embodiment, the sensor of mechanicalstress is a movable part, for example a rod, driven by the ion-exchangematerial, and this movable part is mechanically connected with a movablepart of a potentiometer regulating the electric current.

According to the invention, the sensor can comprise a photo-sensorgenerally placed outside the compartment.

According to a preferred implementation, the sensor comprises aphoto-sensor which comprises a mechanical element, generally placedinside or in contact with the zone, and a photo-detector of thedisplacement of said mechanical element which comprises a transceiver,placed generally outside the compartment, and wherein the compartmentaround the mechanical element has at least one transparent wall (orwindow) so that the optical signal from the transmitter to the receivercan cross said compartment adjacent to the mechanical element.

The description is neither limited to the type of device (design ofmodule, sensor, etc), nor to the supporting members (spring, fixtures,etc) if any, nor to the type of sensor. The electric current controldisclosed here can be applied to different concepts of EDI devices (withmixed bed, with layered or separated beds, etc), and using differention-exchange materials in the device (bed of resin beads, ion-exchangeblocks, etc). The transmission of the signal from the sensor to thecontroller as well as from the controller to the EDI-power supply can bedone by means of wires, as well as by different wireless technologies.The regulation of electric current can also be done regarding theexpansion of the ion-exchange material in a concentrate compartmentand/or in an electrode compartment, if such a measure is considered tobe more advantageous for certain configurations of EDI.

According to the invention, the device can also comprise another sensor,generally different from the sensor according to the invention, which isable to measure the hydraulic pressure of the liquid flow which cancirculate through the zone (and only this hydraulic pressure). If thesensor according to the invention reacts to both the mechanical stresscreated by the expanded ion-exchange material and the hydraulic pressureof liquid, additional measurements of the hydraulic pressure of polarliquid should be deducted from the measurements carried out by thesensor according to the invention. Thus more accurate measurements ofthe dimensional changes of the ion-exchange material can be obtained.

The sensor according to the invention is usually able to measure thehydraulic pressure of the liquid inside the compartment and thedimensional changes of the ion-exchange material while the other sensoris able to measure the hydraulic pressure of the liquid inside thecompartment. For example, if another sensor monitors the pressuredownstream of the compartment, and if the sensor according to theinvention inside the compartment monitors the stress, the measurementsof these two sensors can be used to calculate the mechanical stresscaused by the ion-exchange material. In case the gauge pressuredownstream of the device is close to zero (for example flow to a tank atatmospheric pressure), the measurements of the stress on a sensor placedclose to the outlet of the compartment, for example a diluatecompartment, can be considered as the measurement of the mechanicalstress due to dimensional changes of the ion-exchange material in thiscompartment. Also in case a constant pressure of liquid is provided inwide range of flow rates, e.g. using a pressure regulator or acheck-valve, the additional monitoring of this hydraulic pressure isgenerally not required and a predefined and constant value of hydraulicpressure is usually subtracted from the measurements of the sensorinside the compartment, to deduce the mechanical stress of the resinexpansion.

In a variant, the device according to the invention comprises anapparatus connected to the sensor and, preferably, this apparatusconnected to the sensor is able to analyze the dimensional change of theion-exchange material and to control the electric current conductedthrough said compartment or through the device.

The invention also comprises a method for the removal of ions from apolar liquid wherein at least a part of said polar liquid passes as astream through an electrochemically regenerable ion-exchange materiallocated in a compartment where an electric field is applied so that theions to be removed migrate,

the method comprising a step of controlling the electric currentconducted through said compartment,

the method being characterized in that it includes a step of measuringat least one dimensional change of the ion-exchange material and in thatthe step of controlling the electric current takes into account thisdimensional change of the ion-exchange material.

The step of controlling the electric current is at least related to theelectric current in the compartment, but it can also control the currentin the device in which the compartment is comprised.

In one embodiment, the migration of the ions to be removed is preferablyin a direction opposed to the stream flow through said ion-exchangematerial. Thus, the flow of liquid used for ion removal can be directedopposite, i.e. countercurrent, to the migration of ions inside theion-exchange material. The corresponding ions from the feed stream willbe removed by ion-exchange, will further migrate inside ion-exchangematerial and will finally be released at the electrode to a concentratestream going to waste.

The ion-exchange material is generally continuously regeneratedelectrochemically. Thus, the ions from the feed stream can becontinuously exchanged and a flow substantially free of correspondingsalt ions is obtained.

The regeneration degree of said material is used as a parameter forcontrolling the electric current, via the change of the volume of saidmaterial.

The characteristics of the polar liquid can change over time because ofthe instability of upstream treatment (for example effect oftemperature, scaling, fouling or aging) or by quality changes of waterutilized by the system (change of source by water supplier, seasonalchanges, etc.). Also the flow rate through the EDI can vary during thelifetime of the module. Advantageously, the method of the inventiongives a method operating with all these changing conditions with a goodlevel of control of the electric current.

Typical liquid used as polar liquid is pre-treated water, such aspermeate of reverse osmosis, nanofiltration or ultrafiltration.

The principle of the methods and devices of the present invention usedto remove ionic and ionizable components from a polar liquid can beapplied not only to aqueous electrolyte solutions, but also to solutionsin other polar solvents or in the water/polar solvent mixtures.

Preferably, the maximum allowed mechanical stress which determines themaximum value of electric current for the EDI device is definedexperimentally for each design of EDI device. If this maximum isachieved, then the controller will decrease the electric currentconducted through the compartment to prevent excessive expansion of theresin and subsequent strain on the frame and on membranes. This willdecrease the risks of possible leaks and the energy consumption of thecompartment. A lower limit of mechanical stress can be also set torestrict electric current. For example, if the ratio between the saltform and the regenerated form of the resin decreases, the resin beadsshrink and the mechanical stress received by the sensor can disappear.In this case, the controller should increase the electric currentstrength to reach a value above the set minimum value.

The period of time between the changes of electric current and theexpansion of the resin should be taken into account by the controller.The system can take a long time to reach a steady state, where the resinexpansion corresponds to a new applied current, and this fact must beconsidered in the control of the electric current. The details of thecontrol (regulation) algorithms and communication between the sensor,the controller and the power supply are not described in detail in thisand are easily accessible to one skilled in the art.

Nevertheless, possible ways of current regulation are described herewithout specifying the details of the algorithms.

The expansion of the resin bed in the EDI device is measured withcertain predefined intervals. The time between measurements is to beselected according to module design and dimensions, as well as operatingconditions. It can last from few minutes to few hours of operation.Preferably several measurements are done and an average measurement iscalculated and considered.

A certain range of resin expansion, registered by a sensor, is definedas an “optimal range”, where no adjustment is done and the module isworking under constant electric current.

There are two ranges of “acceptable” expansion out of this optimalrange, where the electric current is regulated. If the expansion islower than what it is in the optimal range, the electric current is tobe increased. The increment of current increase can be predetermined orit can depend on the difference between the measured value of theexpansion and the predefined corresponding optimal value, e.g. theincrement will increase proportionally to this difference. The timebetween the moment when electric current is changed and when a nextmeasurement of expansion is taken into account can be fixed or it canvary, e.g. depending on increment of electric current strength.

If the expansion is in an “acceptable range” but higher than the optimalrange, the electric current is to be decreased in a way similar to theway described above.

An expansion out of the optimal and acceptable ranges is undesirable.When the expansion of the resin bed is unacceptably low, this can leadto a decline of produced water quality. When the expansion of the resinbed is unacceptably high, this can lead to inefficient energyconsumption and possible leaks. If the expansion is unacceptably low,the electric current can be set to a maximal value, e.g. to a presetvalue or the highest current available for the power supply, aiming tofacilitate regeneration of resin and approach resin expansion to theoptimal range. If the expansion is unacceptably high, the electriccurrent can be set to a minimal value, e.g. to a preset value orcomplete switching off the power supply. The expansion in theunacceptable range should be continuously monitored until the measuredvalues move to the acceptable or optimal range.

According to the invention, the step of measuring the dimensional changeof the ion-exchange material is carried out by means of a sensor.

In an embodiment, the sensor comprises a photo-sensor.

In a preferred embodiment, independent or not of the previousembodiment, the sensor comprises a sensor of mechanical stress.

The invention also discloses a method further comprising a step ofmeasuring the hydraulic pressure of the stream flow which passes throughthe ion-exchange material.

Preferably, the step of controlling the electric current takes intoaccount the dimensional change of the ion-exchange material without theinfluence of the hydraulic pressure of the stream flow.

As a variant, the stream flow is regulated by hydrodynamic adjustment ofthe pressure drop in the outgoing stream.

The presence of an ion-exchange membrane is optional. The fact that,optionally, there is an electrochemically regenerable ion-exchangematerial placed in the compartment does not necessarily mean that thismaterial completely fills this compartment. This material generallyfills a zone in the compartment, for example a zone comprised betweentwo ion-exchange membranes, or between an electrode and an ion-exchangemembrane. In any case, the ion-exchange material fills this zonegenerally as a fixed bed of ion-exchange material.

The hydrodynamic resistance of the device, corresponding to the pressuredifference between the entering and the outgoing liquid flows, isclosely linked to the design of the device, as it is known form the oneskilled in the art.

According to the invention, a device containing anion-exchange material,as described above, can be used for efficient removal of salt anionspresent in the feed stream. It is also able to remove weakly dissociatedacids present in the form of non-dissociated molecules, such as carbonicacid (or CO₂), silicic acid, boric acid, etc.

According to the invention, a device filled with cation-exchangematerial, as described above, can be used for efficient removal of saltcations present in the feed stream. It is also able to remove basespresent in the form of non-dissociated molecules, such as NH₄OH (orNH₃), amines, etc.

The device described below can be used for the removal of acids or basesfrom a polar liquid, or for the production of bases or acids from itsaqueous salt solution, exchanging corresponding ions by OH⁻- or H⁺-ions.

The regenerable ion-exchange material is usually a bed of anion-exchange resin. More generally, conventional ion-exchange materialsare resin beads, high mesh beads of ion-exchange resin, powdered resin,as well as fibrous or porous ion-exchangers. They can be provided asbeds or blocks.

For the removal of both cations and anions, i.e. for completedeionization, a solution is the use of two devices in series, one filledwith cation-exchange material and the other filled with anion-exchangematerial. In this case, a preferable sequence of devices in series mustbe defined considering the types of contamination. For typicalcontaminants of natural or treated (for example by reverse osmosis)natural waters, the cation-exchange material—anion-exchange materialsequence is usually advantageous, but is not limited thereto. If wished,both devices could be integrated inside one housing, without beingoutside the scope of the invention.

Another solution, advantageously used for complete deionizationaccording to the invention, lies in the use of a device with liquid flowdirected counter-current to the electromigration of ions inside theion-exchange material, wherein a bipolar electrode or an ion-exchangemembrane, preferably a bipolar membrane, is utilized for the formationof regenerating H⁺-and OH⁻-ions. The use of a bipolar membrane isadvantageous, in a case where the polar liquid is an aqueous solution,because it results only in electrochemically enhanced water dissociationinto H⁺-and OH⁻-ions without formation of gases and other by-products asoccurs with electrodes.

The techniques of the present invention will be readily understood byconsidering the following detailed description in conjunction with theaccompanying drawings, in the case of an aqueous solution to bedeionized, in which:

FIG. 1 is a schematic representation of the method according to theinvention using any deionization device according to the invention,

FIG. 2 is a schematic representation of a first implementation of adeionization device according to the invention,

FIG. 3 is a schematic representation of a second implementation of adeionization device according to the invention, when the compartment isfull of resin beads,

FIG. 4 is a schematic representation of the second implementation of thedeionization device according to the invention, when the compartment isfull of resin beads, and a mechanical stress is transmitted to theframe,

FIG. 5 is a schematic representation of a second implementation of thedeionization device according to the invention, when the compartment isnot completely full of resin beads, and

FIG. 6 is a schematic representation of a third implementation of adeionization device according to the invention.

To facilitate understanding, identical reference numerals have beenused, when possible, to designate identical elements that are common tothe Figures. The drawings are not to scale and the relative dimensionsof various elements in the drawings are depicted schematically and notto scale.

In all the Figures, the compartment is defined by its frame.

FIG. 1 is a schematic representation of the method according to theinvention of an EDI device 2 according to the invention.

The device 2 can be used for the removal of anions or for the removal ofcations, as well for complete deionization according to the method ofthe invention.

The entering polar liquid flow (F arrow) enters the device 2 through theinlet 4. The deionized liquid flow or diluate (D arrow) passes out ofthe device 2 through the outlet 6. Concentrate flow (C arrow) can exitby the outlet 5. Two end plates 7 and 8, each one comprising oneelectrode, define a module (7, 8) of compartments (9, 14′), all thecompartments 9 and 14′ being filled with ion-exchange material (notshown) and stacked by the end plates 7 and 8. The compartment 14′ isidentical to any other compartment 9 except that a mechanical stresssensor 1′ is placed inside it, preferably on a wall and close to theoutlet 6. This mechanical stress sensor 1′ measures the expansion ofresin, and provides a signal transmitted to an electronic device orcontroller 10 via an apparatus 100, which is a Quantity Transmitter (QT)apparatus. This enables a control of the electric current applied to theEDI device 2, by the means of a power supply 11. The electric current isconducted from the power supply 11 to the EDI device 2 through theelectric wires 12 and 13.

According to the invention, it would be possible to have a sensor 1′ inmore than one compartment.

The interdependence of electric current strength and resin expansion canbe presented as follows: an increase of electric current through the EDIdevice 2 implies an increase of regeneration degree of the resin. Thisincrease of regeneration degree of the resin implies an increase of theresin swelling giving rise to stronger expansion of said resin. Thecontrol according to the invention is based on the measurement of thatexpansion of resin bed inside the EDI device, and acts on the strengthof electric current.

FIG. 2 is a schematic representation of a first implementation of an EDIdevice 20 according to the invention. Only a part of this device 20 isrepresented. This device 20 comprises a frame 14 defining a compartment14 and a movable flow-through electrode 15. The compartment 14 is adiluate compartment, completely filled with an ion-exchange material,which is shown as a bed of a resin 17. The polar liquid flow enters thecompartment 14 by the inlet 4 (F arrow). There is an outlet 5 for theoutgoing liquid rinsing the electrode 15 (C arrow). The liquid flow isdirected counter-current to the electromigration of ions inside theion-exchange material 17. A sensor 1, entirely placed in a zone Z₂₀ ofthe compartment 20, comprises a spring 3 present between the movableelectrode 15 and the sensor of mechanical stress 16. This sensor ofmechanical stress 16 is fixed perpendicularly and connected to a wire 26connected to the controller (not represented). In this representation,the spring 3 pushes the electrode 15 so that this electrode 15 stays incontact with the ion-exchange material 17. If the ion-exchange material17 inside the compartment 14 changes the expansion by swelling, theelectrode 15 will move and the stress transmitted to the sensor 16 willchange. This will lead to a detection of this movement and an estimationof the regeneration degree of the resin. The spring 3 transmits themechanical stress from the electrode 15 to the sensor of mechanicalstress 16.

For example, if the volume of the resin decreases, the electrode 15 willbe moved by the spring 3 in the direction to the resin 17. Thus, themechanical stress transmitted through the spring 3 to the sensor 16 willbe reduced.

In case the set lowest mechanical stress is approached, the controllercan increase the electric current in order to increase the regenerationdegree of the resin 17 whose volume will increase.

This configuration would allow using an ion-exchange material with a lowcross-linking degree, which usually shows stronger expansion byswelling.

FIGS. 3, 4 and 5 are schematic representations of a secondimplementation of a deionization device 22 (partially shown) accordingto the invention.

The device 22 comprises a compartment 14′ defined by its frame, filledby an ion-exchange material 17′ as a bed of resin beads. The sensor 1′,according to the invention, is placed entirely inside a zone Z of thecompartment 14′. The sensor 1′ comprises a spring 3′, a porous bar 18which is a flow distributor, and a sensor of mechanical stress 19, inthe form of a T element. This porous bar 18 confines the bed of theresin 17′ from one side of the compartment 14′. The flow stream (Farrow) flows through the bed of beads 17′ uniformly distributed insidethe compartment 14′, passes through the porous bar 18, and outgoes thecompartment 14′ by the outlet 5′a upstream of the porous bar 18. Thesensor of mechanical stress 19 is fixed on the bar 18 whose movementsare transmitted by the spring 3′ from the side opposite to the resin bed17′. The porous bar 18 can be in plastic material of certain elasticity.

In the case of FIG. 3, the conditions in terms of electric current arenormal. The resin expansion is normal: it is within an “optimal range”.This is a steady state operation, and the electric current is constant.

In case of excessive expansion of the ion-exchange material shown inFIG. 4, a mechanical stress will be transmitted to the bar 18, which isslightly deformed and transmits a mechanical stress to the sensor 19.Deformation is detected. However the resin expansion is still within the“acceptable range”, and the electric current is decreased. If the resinexpansion enters a value outside the acceptable range, the electriccurrent would be switched off.

FIG. 5 is another schematic representation of the second implementationof the deionization device according to the invention. The differencewith FIGS. 3 and 4 is that the compartment 14′ is not completely filledwith resin beads. A bed of beads 17′a comprises a zone Z′ which is notcompletely filled with beads. This zone Z′ could represent the upperzone of a fluidized bed of the beads. It is a zone of increasedelectrical resistance. No mechanical stress is transmitted to the sensor1′ and the electric current needs to be increased.

FIG. 6 is a schematic representation in perspective of a thirdimplementation of the deionization device 27 according to the invention,where only one compartment 14″ is shown. The compartment 14″ isrepresented very schematically, in order how a photo-sensor isimplemented according to the invention.

In this case, a sensor according to the invention 1″ comprises aphoto-sensor which comprises a transmitter of optical signal or light 23(as represented in FIG. 6, in front of the compartment 14″), a receiver24 (as represented in FIG. 6, behind the compartment 14″), and ananalyzer 25 which is connected to both the transmitter 23 and thereceiver 24. The analyzer 25 is connected to a controller (not shown). Aspring 3′ is fixed between the compartment 14″ and a movable plate 18″.The movable plate 18″ is considered here as a part of the sensor 1″. Theion-exchange material 17″, in the form of resin beads, is provided as abed in the compartment 14″. The bed of beads 17″ fills the compartmentunder the movable plate 18″ which fixes the position of the resin bed17″ inside the compartment 14″. An anion-exchange membrane 26 and acation-exchange membrane 27 define two side walls of the compartment14″, respectively the right wall and the left wall as represented inFIG. 6. The movable plate 18″ is detectable through the transparentwindow 28. The transparent window 28 forms a part of the front wall (asrepresented in FIG. 6) compartment 14″. The photo-sensor (23, 24, 25) isplaced outside the compartment 14″. It is able to detect small changesof the plate 18″ position, corresponding to the dimensional changes ofthe volume of the resin 17″, making it possible to control the electriccurrent.

1. System for the removal of ions from a polar liquid, comprisingelectrodes; at least one compartment which comprises at least one inletfor an entering polar liquid flow and at least one outlet for anoutgoing deionized liquid flow, in which said compartment anelectrochemically regenerable ion-exchange material fills a zone throughwhich zone a liquid flow is able to pass; at least one sensor of atleast one dimensional change of the ion-exchange material filling saidzone; and a controller responsive to said sensor.
 2. The systemaccording to claim 1, wherein said sensor comprises a photo-sensor. 3.The system according to claim 1, wherein said sensor comprises a sensorof mechanical stress.
 4. The system according to claim 1, wherein saidsensor comprises a photo-sensor which comprises a mechanical element anda photo-detector of the displacement of said mechanical element whichcomprises a transmitter and a transceiver, and wherein said compartmenthas at least one transparent wall so that an optical signal from saidphoto-detector can cross said compartment adjacent to said mechanicalelement.
 5. The system according to claim 1, comprising another sensorwhich is able to measure the hydraulic pressure of the liquid flow whichcan circulate into the zone.
 6. The system according to claim 1, furthercomprising a power supply, and wherein said controller control theelectric current to said compartment from said power supply in responseto said sensor.